Hi John,
From my truck driving days, I remember that if I didn't drain the air tanks (that were for the air brakes) for a few days, the first thing that came out was a milky oily substance. This was followed by water that was slightly contaminated with the milky-oily stuff, then air. When you had clean air coming out, your air tanks were "drained".
Note that compressors tend to make this stuff in the process of compressing the air. What you're seeing isn't unusual, but you'd prefer not to have any of it in your system.
We've got a 2004 and it's got an air dryer which purges some little puffs of air from time to time as you are driving or idling the rig. This purges the oily and watery stuff so the air system contains only air. You may or may not have that air dryer in your 1998.
Assuming that the value you're working with is the correct valve, you should drain the oily stuff, then the water. To eliminate a mess, you could probably drain it into some kind of bottle or jar or milk carton. As you have probably guessed, you should do this draining more frequently. If done daily when traveling, you'll only get a fraction of a second of any oily or watery stuff, then nice clean air.
Good Luck!
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Mike and Mike (Michele)
2017 Winnebago Tour 42HD
Previously: 2004 Alpine 34 FDDS
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