You should be sure that the outside spray faucet gets winterized and leave both hot and cold open, the low point drains (next to it in our rig) also. I have left them open or closed at various times doesn't matter. I would not advise leaving any of your drain valves open, black, grey or fresh, they will freeze open, better to freeze closed, then warm up as the rig does. In our rig it is practically impossible to get all the water out of the fresh tank anyway.
You actually have 2 valves on your water heater, the one you closed and a mixing valve that should be closed anyway. You have the 16 gallon (ten gallon GE heater with high thermostat and mixing valve to produce 16 gallons) Atwood XT. There may be a problem with the mixing valve after winterizing. I replaced the mixing valve twice(under warranty) right after de-winterizing. Note that this was 2 times in 2 years with 6 or 8 winterizations. Well, the third time it failed (after winterizing) I was out of warranty, so I had it downgraded to a standard 10 gallon water heater. This involved some plumbing, a lower temp thermostat, and some problems with the circuit board, which had to be replaced(probably).
Symptoms of failure of the mixing valve were a burst of hot water as you first turn on the faucet then no hot water at all, just lukewarm. So after you de-winterize I would advise checking to see that you do not have a mixing valve failure. I am not sure why it fails, the valves go back to Atwood if replaced by a certified tech, but I think that there is water in the valve which does not get mixed with antifreeze and damages the valve. This is just a theory, I neither know nor care anymore. It may also have something to do with the expandable wax in the valve (expands with heat) being frozen, it is not clear from the manufacturer's site that these valves are supposed to be used in cold conditions.
Another known problem with them is small particles can get in the valve and get stuck, sometimes pounding on the valve with a hammer (not too vigorously, regardless of how mad you are) will break them loose for a while. A very good filter for your water will help.
For de-winterizing just run a lot of water through, every faucet should show clear, before you put water in the heater. Hot antifreeze does not smell good. Be sure to close the outside faucet both hot and cold. Note that this is not obvious because the sprayer will be off. If you do not you will have similar symptoms as a failed valve: lukewarm water. BTDT.