I also have rebuilt many car and motorcycle calipers. Sometimes to only way to get the boot on is to remove the caliper from the rotor, use the pressure from the brake master cylinder to push out the piston completely, install the boot on the caliper side, carefully reinstall the piston, install the boot on the piston before you retract it fully into the caliper. This is a 2 man job due to the weight of RV calipers and someone the push on the brake pedal. Then rebleed the brake system.
Or try just siliconing the outer boot edge to the caliper after cleaning it well???

The boot is just there to keep water and dirt off the outer edge of the piston.
I made ball joint covers for my F53 out of inner tubes and clamps after the originals dry rotted.