Check out Reflectix panels:
https://www.reflectixinc.com/
I've not used them yet but many people swear by them. You place them in your windows (and car windows) to reflect the heat away from the interior. They work best when secured outside, particularly the large windows, because they never let the heat get inside but most people seem to just unfold them inside and place them against the windows.
Magneshade is another people seem to love but they are a lot more expensive. You apparently secure magnets to the inside of your windows and these things stick through the glass to the outside. No ladder needed to install them.
https://magneshade.com/
Ray