I do not know how your RV is wired but I know how to find out.
Option 1: All batteries are connected together
Option 2: One set is connected to inverter 1, the other to inverter 2
NOW: I also don't know what model Xantrex you have so I will give you two methods for figuring it out.
NOTE: With these large inverters,, Unless you have a second charging system as I do, Whatever charges a battery, also discarges it.
Step one.. If you can DISABLE the charger on ONE and only one inverter.. Do so.
Wait 10 minutes or so (The length depends on load, if a load is present 10 minutes works. Otherwise an hour might be better.)
If the Xantrex has a remote that displays battery voltage,, are they the same, or is one over 13 volts and the other under (IE: 12.6)
If the Xantrex does not have a voltage display, Use your digital multi-meter to measure the battery voltage in each bank.. Again the same or is one over and one under 13 volts?
IF they are Over/Under, than one battery bank is hooked to one inverter and the other to the other, This will be the same no matter if they are charging off shore/generator power or if they are powering your "house". one bank per device.
IF they are the same voltage.. Then the two banks are parallel.
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Home is where I park it!
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