For comparison, 2006 Ford F250 CC LWB 4x4 with 5.4L Gas engine & 3.73 gears, currently 275,000 miles on it (very durable). Like you, pulled a 14,000 lb. 5er 10% of the time. She gets 14.5mpg on highway empty, and 7.5-8.0mpg pulling the 5er at 70mph in southern flat states.
As you will note in my signature, I have purchased an F350 with 6.7L PSD because I was headed to Colorado and the 5.4L gas w/3.73 gears wasn't going to cut it.
The newer 6.2L gas has better hp/torque output and should be more efficient on fuel economy. However, your empty mpg probably won't be much, if any, better than mine due to the 4.30 gears. So, I would expect the same mpg as my '06 F250 but you will have an easier time pulling the weight. Like the other folks, I would not imagine the Chevy would do much better or worse.
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2012 Cardinal 3675RT
2014 Ford F350 CC KR SRW FX4 6.7L 3.55 E-Locker
Austin County, "Colonial Capital of Texas"
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