I'd first remove, clean, and inspect all battery connections, including those to ground. After batteries have all been charged, you can do a specific gravity test of each battery cell to see if you have a dead cell. Any battery seller or auto parts store usually will do a load test on the battery for free to determine if it needs replacement.
I don't think your RV had the wiring to charge the chassis battery from converter/charger, you might want to add a
Trik-L-Start to keep battery charged.
If the battery checks out O.K., next you'll have to determine if your wiring modifications have set up a drain on the chassis battery. Measuring the amp draw with ignition off, then removing fuses, one at a time, to see which circuit has the heavy drain would be the way to track down the issue.