Hey Chris,
Welcome to the forum! You'll learn a lot here.
As with any electrical issue, I first start with the wiring, plugs and fuses to ensure the circuits are open. What you are describing suggest that the water heater is heating up a wire near the heating element, or there is a short somewhere. Thus, tripping the breaker......I suggest starting with wiring at the tank and move from there. You could start the water heater on electric, then open the panel and watch it to see.
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2016 Thor Palazzo 33.2
14 Honda CRV, Roadmaster Tow Bar, Air Force 1
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