The Volt reading is the voltage at the batteries with whatever charge device is connected. To get a good idea as to the state of charge (SOC) the batteries should rest for ~ an hour with no charge or load.
The different device vaty well chare at different rates thus the different reading.
The Amber light is telling you it is Bulk Charging Mode,
The DC Volts are at 14 V almost ready to go to Float Mode.
The DC Amps says it is charging at 25 Amps
The far right geen LED say you have selected to allow 50 Amp AC power to the Inverter/Charger.
When the Batteries are fully charged they will go to Float Mode, the green LED above the 3rd batt. icon will come on the amber will go off. The volts will be ~14V and the amps will drop to a lower value.
Looks like it is working just fine.
If you don't have the manual they are available online. You should read and check the setting against the type and size of you House Batteries.
Here is mine your may be a different model
http://www.xantrex.com/documents/Dis...nersManual.pdf