First of all, you need to include or post the year, make and model of your RV... someone reading your posting may have the same RV... if you add it to your signature lines then it will be automatically added to the end of each posting...
To answer your question...
If you are going to use the fill-it-up method then this will help...
https: //
www.walmart.com/ip/P3-International-P0550-Save-A-Drop-Water-Meter/19885585
I've also seen it on Amazon and a few years ago at big orange (Home Depot)...
Next, if you have physical access to the tanks, and if they are square sided then it's fairly easy... I used this method with my Class A... (shades of 1960s grade school math and high school physics)...
I'll use my fresh water tank as an example...
The tape measure says the outside dimensions are 22.5 inches wide by 15.5 inches high by 44.5 inches deep
22.5 times 15.5 times 44.5 is 15519.375 cubic inches
15519 divided by 231 (the number of cubic inches in a gallon) = 67.18
but we are using outside dimensions for simplicity and that ignores the thickness of the tank walls... and the thickness (especially of the bottom and the sides) reduces the volume... so call it around 65-66 gallons.
If you have a tank with an odd shape that can be approximated with multiple cubes, i.e. a smaller cube on top of a larger cube, or a small cube on the end of a large cube then you can calculate the volume of each section and then add the resulting numbers...
Some black and grey tanks are tapered on the bottom with the "fat" end or low point at the drain fitting (to assist in dumping)... just measure the height of the short end and the height of the tall end and split the difference. the volume will not be exact, but it will be usable.
A few months after I calculated 65-66 gallons I found a old brochure from the vintage of my coach and it said 65 gallons. Close enough...
Later on using a meter (like the one shown in the walmart webpage above) I found that it overflowed right around 62 and a half... Must have shrunk with age... Or maybe the overflow tube location cost some volume. Or maybe the marketing weasels rounded the numbers up...
Mike