Could possibly be oil and tire rubber from the road surface sticking to the Catalytic Converter and exhaust pipe.
See:
http://www.irv2.com/forums/f85/hot-o...ep-187493.html
Upon start, the toad's Catalytic Converter gets hot - fast...so hot that (we all should know) it can start a grass fire.
It is most common in the west where lower rain levels rarely clean the roadway.
Can Happen to flat towed or dolly towed (like ours).
Safe travels