The solar voltage is independent of the battery voltage. The solar charge controller takes the solar input however it comes in, then converts that to the battery voltage you program (or it senses).
If you change from 12v battery to 24v battery you need to get a new inverter that will accept 24v since there is no efficient and inexpensive way to convert the 24v to 12v at the amperages the inverter can pull. So stick to 12v unless you want to change more components and add a DC-DC to drop the 24v to 12v for the trailer house circuits use.
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2021 Flagstaff 21DS behind a 2015 Silverado 2500HD
Renogy bits: 3000W Inverter/Charger, 400Ah LiFePo4, 40A DC-to-DC. Rich Solar bits: 400W of panels, 40A MPPT. Misc bits: LevelMatePro+, SolidRemote based wireless controlled LED storage lighting
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